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Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α,ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation, [Cp∗(CO)2Fe]+
(Elsevier, 2012)
A series of water-soluble alkylaminopentamethylcyclopentadienyliron dicarbonyl complexes, [Cp ∗ (CO) 2 Fe{NH 2 (CH 2 ) n CH 3 }]BF 4 (n=2–6; Cp ∗ =η 5 -C 5 Me 5 ) and the diaminopropane bridged complex, [{Cp ∗ (CO) 2 Fe} ...
Syntheses, structural elucidation and reactions of allylamino compounds of the type, [η5-C5R5(CO)2Fe(NH2CH2CHCH2)]BF4
(Pergamon, 2012)
The reaction of 3-aminoprop-1-ene (allylamine) with the etherate complexes [(n5-C5R5)(CO)2Fe(L)]+(R = H; L = Et2O; R = CH3; L = THF) have been investigated and found to give air stable allylamino com-plexes [(n5-C5R5)(CO ...
Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α, ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation,[Cp∗(CO) 2 Fe]+
(Elsevier, 2012)
A series of water-soluble alkylaminopentamethylcyclopentadienyliron dicarbonyl complexes, [Cp∗(CO)2Fe{NH2(CH2)nCH3}]BF4 (n = 2–6; Cp∗ = η5-C5Me5) and the diaminopropane bridged complex, [{Cp∗(CO)2Fe}2{μ-NH2(CH2)3NH2}](BF4)2 ...
Dicarbonyl (η5-cyclopentadienyl)(hexamethylenetetramine-κN1) iron (II) tetrafluoridoborate
(International Union of Crystallography, 2012)
In the structure of the title compound, [Fe(C5H5)(C6H12N4)-(CO)2]BF4, the arrangement around the FeIIatom corresponds to that of a three-legged piano stool. The cyclopenta-dienyl ligand occupies three coordination sites ...
Regioselective reactions of electrophilic iron dicarbonyl cations, [(η5-C5R5)(CO)2Fe]+ (R = H, CH3) with heterofunctional amine ligands
(Elsevier, 2012)
The reactions of the ether salts [(η5-C5R5)(CO)2Fe(E)]BF4, (R = H, E = Et2O; R = CH3, E = THF) with various ligands possessing two different coordination sites have been investigated. It was established that [(Cp(CO)2Fe(OEt2)]BF4 ...
Dicarbonyl (hexamethylene-1, 3, 5, 7-tetramine-κN1)(η5-pentamethylcyclopentadienyl) iron (II) tetrafluoridoborate
(International Union of Crystallography, 2012)
In the title compound, [Fe(C10H15)(C6H12N4)(CO)2]BF4, the arrangement around the FeIIatom corresponds to a three-legged piano stool. The pentamethylcyclopentadienyl (Cp*) ligand occupies three coordination ...