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Syntheses, structural elucidation and reactions of allylamino compounds of the type, [η5-C5R5(CO)2Fe(NH2CH2CHCH2)]BF4
(Pergamon, 2012)
The reaction of 3-aminoprop-1-ene (allylamine) with the etherate complexes [(n5-C5R5)(CO)2Fe(L)]+(R = H; L = Et2O; R = CH3; L = THF) have been investigated and found to give air stable allylamino com-plexes [(n5-C5R5)(CO ...
Dicarbonyl (η5-cyclopentadienyl)(hexamethylenetetramine-κN1) iron (II) tetrafluoridoborate
(International Union of Crystallography, 2012)
In the structure of the title compound, [Fe(C5H5)(C6H12N4)-(CO)2]BF4, the arrangement around the FeIIatom corresponds to that of a three-legged piano stool. The cyclopenta-dienyl ligand occupies three coordination sites ...
(μ-Ethane-1, 2-diamine-κ2N: N′) bis [dicarbonyl (η5-cyclopentadienyl) iron (II)] bis (tetrafluoridoborate)
(International Union of Crystallography, 2011)
The asymmetric unit of the title compound, [Fe2(C5H5)2- (C2H8N2)(CO)4](BF4)2, contains two half-cations, each
located on a center of symmetry, and two tetrafluoridoborate anions. The iron atoms adopt a three-legged ...