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Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls

M’thiruaine, Cyprian M.; Friedrich, Holger B.; Nyawade, Eunice A.; Omondi, Bernard (Inorganica Chimica Acta, 2014)

The new 2,4,6-trimethylaniline complexes [Cp∗Fe(CO)2(NH2C6H2(CH3)3)]+ (3) and [CpFe(CO)2(NH2C6H2(CH3)3)]+ (4) (Cp∗ = η5-C5(CH3)5; Cp = η5-C5H5) have been synthesized and isolated in high yields as tetrafluoroborate salts. ...