Browsing by Author "M'thiruaine, Cyprian M"
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Acetonitriledicarbonyl (η5-pentamethylcyclopentadienyl) iron (II) tetrafluoridoborate
M'thiruaine, Cyprian M; Friedrich, Holger B {et al} (International Union of Crystallography, 2011)In the structure of the title compound, [Fe{5-C5(CH3)5}- (NCCH3)(CO)2]BF4, the arrangement of ligands around the Fe atom is in a pseudo-octahedral three-legged piano-stoolfashion in which the pentamethylcyclopentadienyl ... -
Dicarbonyl (hexamethylene-1, 3, 5, 7-tetramine-κN1)(η5-pentamethylcyclopentadienyl) iron (II) tetrafluoridoborate
M'thiruaine, Cyprian M; Friedrich, Holger B; Changamu, Evans O; Fernandes, Manuel A (International Union of Crystallography, 2012)In the title compound, [Fe(C10H15)(C6H12N4)(CO)2]BF4, the arrangement around the FeIIatom corresponds to a three-legged piano stool. The pentamethylcyclopentadienyl (Cp*) ligand occupies three coordination ... -
Dicarbonyl (η5-cyclopentadienyl)(hexamethylenetetramine-κN1) iron (II) tetrafluoridoborate
M'thiruaine, Cyprian M; Friedrich, Holger B; Omondi, Bernard (International Union of Crystallography, 2012)In the structure of the title compound, [Fe(C5H5)(C6H12N4)-(CO)2]BF4, the arrangement around the FeIIatom corresponds to that of a three-legged piano stool. The cyclopenta-dienyl ligand occupies three coordination sites ... -
[HTML] from iucr.org (μ-Formato-κ2O: O′) bis [dicarbonyl (η5-cyclopentadienyl) iron (II)] tetrafluoridoborate.
M'thiruaine, Cyprian M; Friedrich, Holger B; Changamu, Evans O; Omondi, Bernard (International Union of Crystallography, 2011)In the structure of the title compound [Fe(2)(C(5)H(5))(2)(CHO(2))(CO)(4)]BF(4), each Fe(II) atom is coordinated in a pseudo-octa-hedral three-legged piano-stool fashion. The cyclo-penta-dienyl ligand occupies three fac ... -
A structural investigation of the D2O solvated, acetone solvated and nonsolvated 1,4-Diazabicyclo[2.2.2]octane complexes of the half sandwich moiety [(η5-C5H5)(CO)2Fe]
Changamu, Evans O; Omondi, Bernard; M'thiruaine, Cyprian M; Friedrich, Holger B (Sabinet, 2013)Two new solvates of the dinuclear salt {(η5-C5H5)(CO)2Fe}2(μ-DABCO)](BF4)2 (DABCO = 1,4-diazabicyclo[2.2.2]octane); 1 (D2O solvate) and 2 (acetone solvate), and the mononuclear salt [(η5-C5H5)(CO)2Fe(DABCO)]BF4, 3, have ... -
(μ-Ethane-1, 2-diamine-κ2N: N′) bis [dicarbonyl (η5-cyclopentadienyl) iron (II)] bis (tetrafluoridoborate)
M'thiruaine, Cyprian M; Friedrich, Holger B; Changamu, Evans O; Omondi, Bernard (International Union of Crystallography, 2011)The asymmetric unit of the title compound, [Fe2(C5H5)2- (C2H8N2)(CO)4](BF4)2, contains two half-cations, each located on a center of symmetry, and two tetrafluoridoborate anions. The iron atoms adopt a three-legged ... -
(μ-Formato-κ2O: O′) bis [dicarbonyl (η5-cyclopentadienyl) iron (II)] tetrafluoridoborate
M'thiruaine, Cyprian M; Friedrich, Holger B; Changamu, Evans O; Omondi, Bernard (International Union of Crystallography, 2011)In the structure of the title compound [Fe(2)(C(5)H(5))(2)(CHO(2))(CO)(4)]BF(4), each Fe(II) atom is coordinated in a pseudo-octa-hedral three-legged piano-stool fashion. The cyclo-penta-dienyl ligand occupies three fac ...