Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls
| dc.contributor.author | M’thiruaine, Cyprian M. | |
| dc.contributor.author | Friedrich, Holger B. | |
| dc.contributor.author | Nyawade, Eunice A. | |
| dc.contributor.author | Omondi, Bernard | |
| dc.date.accessioned | 2016-06-28T20:46:20Z | |
| dc.date.accessioned | 2020-02-06T13:03:44Z | |
| dc.date.available | 2016-06-28T20:46:20Z | |
| dc.date.available | 2020-02-06T13:03:44Z | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 0020-1693 | |
| dc.identifier.uri | http://repository.must.ac.ke/handle/123456789/907 | |
| dc.description.abstract | The new 2,4,6-trimethylaniline complexes [Cp∗Fe(CO)2(NH2C6H2(CH3)3)]+ (3) and [CpFe(CO)2(NH2C6H2(CH3)3)]+ (4) (Cp∗ = η5-C5(CH3)5; Cp = η5-C5H5) have been synthesized and isolated in high yields as tetrafluoroborate salts. They have been fully characterized by NMR, IR, elemental analysis, thermogravimetric analysis and X-ray crystallography. For comparison purpose, the molecular structure of [CpFe(CO)2(NH2CH2C6H4OCH3)]+ (5) has been determined and discussed in relation to those of 3 and 4. Compounds 3 and 5 crystallize in monoclinic P21/c space group, while 4 crystallizes in triclinic View the MathML sourceP1¯ space group. Compounds 3 and 4 exhibited considerable thermal stabilities at temperatures as high as 170 °C, which is close to their melting points. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Inorganica Chimica Acta | en_US |
| dc.subject | 2,4,6-Trimethylaniline | en_US |
| dc.subject | Pentamethylcyclopentadienyl iron(II) | en_US |
| dc.subject | Cyclopentadienyliron(II) | en_US |
| dc.subject | Dicarbonyl complexes | en_US |
| dc.title | Syntheses and structural characterization of 2,4,6-trimethylaniline complexes of iron carbonyls | en_US |
| dc.type | Article | en_US |
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