| dc.contributor.author | M’thiruaine, Cyprian M | |
| dc.contributor.author | Friedrich, Holger B | |
| dc.contributor.author | Changamu, Evans O | |
| dc.contributor.author | Bala, Muhammad D | |
| dc.date.accessioned | 2018-10-17T12:24:07Z | |
| dc.date.accessioned | 2020-02-06T13:15:09Z | |
| dc.date.available | 2018-10-17T12:24:07Z | |
| dc.date.available | 2020-02-06T13:15:09Z | |
| dc.date.issued | 2012 | |
| dc.identifier.uri | http://repository.must.ac.ke/handle/123456789/928 | |
| dc.description.abstract | A series of water-soluble alkylaminopentamethylcyclopentadienyliron dicarbonyl complexes, [Cp∗(CO)2Fe{NH2(CH2)nCH3}]BF4 (n = 2–6; Cp∗ = η5-C5Me5) and the diaminopropane bridged complex, [{Cp∗(CO)2Fe}2{μ-NH2(CH2)3NH2}](BF4)2 have been synthesized and fully characterized. [Cp∗(CO)2Fe{NH2(CH2)5CH3}]BF4 undergoes counteranion exchange with sodium tetraphenylborate in both aqueous and organic media to give water insoluble [Cp∗(CO)2Fe{NH2(CH2)5CH3}]BPh4. The molecular structures for compounds [Cp∗(CO)2Fe{NH2(CH2)3CH3}]BF4 and [{Cp∗(CO)2Fe}2{μ-NH2(CH2)3NH2}](BF4)2 have been determined by single crystal X-ray crystallography and show that they crystallize in the orthorhombic and monoclinic crystal systems, respectively | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.subject | α,ω-Diaminoalkanes 1-Aminoalkanes Alkylaminopentamethylcyclopentadienyliron dicarbonyl Water-soluble organometallic compounds | en_US |
| dc.subject | α,ω-Diaminoalkanes 1-Aminoalkanes Alkylaminopentamethylcyclopentadienyliron dicarbonyl Water-soluble organometallic compounds | en_US |
| dc.title | Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α, ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation,[Cp∗(CO) 2 Fe]+ | en_US |
| dc.type | Article | en_US |
